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Permitted Oxygen Abundances and the Temperature Scale of Metal-poor Turnoff Stars
We use high-quality VLT/UVES published data of the permitted O I tripletand Fe II lines to determine oxygen and iron abundances in unevolved(dwarfs, turnoff, subgiants) metal-poor halo stars. The calculationshave been performed both in LTE and non-LTE (NLTE), employing effectivetemperatures obtained with the new infrared flux method (IRFM)temperature scale by Ramírez & Meléndez, and surfacegravities from Hipparcos parallaxes and theoretical isochrones. A newlist of accurate transition probabilities for Fe II lines, tied to theabsolute scale defined by laboratory measurements, has been used.Interstellar absorption has been carefully taken into account byemploying reddening maps, stellar energy distributions andStrömgren photometry. We find a plateau in the oxygen-to-iron ratioover more than 2 orders of magnitude in iron abundance(-3.2<[Fe/H]<-0.7), with a mean [O/Fe]=0.5 dex (σ=0.1 dex),independent of metallicity, temperature, and surface gravity. The flat[O/Fe] ratio is mainly due to the use of adequate NLTE corrections andthe new IRFM temperature scale, which, for metal-poor F/early G dwarfsis hotter than most Teff scales used in previous studies ofthe O I triplet. According to the new IRFM Teff scale, thetemperatures of turnoff halo stars strongly depend on metallicity, aresult that is in excellent qualitative and quantitative agreement withstellar evolution calculations, which predict that the Teffof the turnoff at [Fe/H]=-3 is about 600-700 K higher than that at[Fe/H]=-1. Recent determinations of Hα temperatures in turnoffstars are in excellent relative agreement with the new IRFMTeff scale in the metallicity range -2.7<[Fe/H]<-1,with a zero-point difference of only 61 K.

The non-LTE line formation of neutral carbon in late-type stars
Aims.We investigate the non-Local Thermodynamic Equilibrium (non-LTE)line formation of neutral carbon in late-type stars in order to removesome of the potential systematic errors in stellar abundance analysesemploying C i features. Methods: .The statistical equilibrium codeMULTI was used on a grid of plane-parallel 1D MARCS atmosphericmodels. Results: .Within the parameter space explored, thehigh-excitation C i lines studied are stronger in non-LTE due to thecombined effect of line source function drop and increased line opacitydue to overpopulation of the lower level for the transitions considered;the relative importance of the two effects depends on the particularcombination of T{eff}, log g, [Fe/H] and [C/Fe] and on theanalysed C i line. As a consequence, the non-LTE abundance correctionsare negative and can be substantially so, for example ˜ -0.4 dex inhalo turn-off stars at [Fe/H]˜ -3. The magnitude of the non-LTEcorrections is rather insensitive to whether inelastic H collisions areincluded or not. Conclusions: .Our results have implications onstudies of nucleosynthetic processes and on Galactic chemical evolutionmodels. When applying our calculated corrections to recent observationaldata, the upturn in [C/O] at low metallicity might still be present(thus apparently still necessitating contributions from massive Pop. IIIstars for the carbon production), but at a lower level and possibly witha rather shallow trend of ˜ -0.2 dex/dex below [O/H]˜ -1.

A catalog of rotational and radial velocities for evolved stars. IV. Metal-poor stars^
Aims.The present paper describes the first results of an observationalprogram intended to refine and extend the existing v sin i measurementsof metal-poor stars, with an emphasis on field evolved stars.Methods: .The survey was carried out with the FEROS and CORALIEspectrometers. For the v sin i measurements, obtained from spectralsynthesis, we estimate an uncertainty of about 2.0 km s-1. Results: .Precise rotational velocities v sin i are presented for alarge sample of 100 metal-poor stars, most of them evolving off themain-sequence. For the large majority of the stars composing the presentsample, rotational velocities have been measured for the first time.

Potassium abundances in nearby metal-poor stars
Aims.The potassium abundances for 58 metal-poor stars are determinedusing high-resolution spectroscopy. The abundance trends in stars ofdifferent population are discussed. Methods: .All abundanceresults have been derived from NLTE statistical equilibrium calculationsand spectrum synthesis methods. Results: .The NLTE corrections aresignificant (-0.20 to -0.55 dex) and they depend on the effectivetemperatures and surface gravities. The potassium abundances of thindisk, thick disk and halo stars show distinct trends, such as in thecase of the α-elements. [K/Fe] gradually increases with a decreasein [Fe/H] for thin disk stars, [K/Fe] of thick disk stars is nearlyconstant at [K/Fe] ~ +0.30 dex; halo stars also have nearly constantvalues of [K/Fe] ~ +0.20 dex. Conclusions: .The deriveddependence between [K/Fe] and [Fe/H] is in agreement with thetheoretical prediction of published model calculations of the chemicalevolution of the Galaxy. The nearly constant [K/Mg] ratio with smallscatter suggests that the nucleosynthesis of potassium is closelycoupled to the α-elements.

Na, Mg and Al abundances as a population discriminant for nearby metal-poor stars
Aims.Parameters for 55 nearby metal-poor stars are determined usinghigh-resolution spectroscopy. Together with similar data taken from arecent analysis, they are used to show trends of their Galacticevolution with stellar [Fe/H] or [Mg/H] abundances. The separation ofabundance ratios between disk and halo stars is used as a basiccriterion for population membership. Methods.After carefulselection of a clean subsample free of suspected or known binaries andpeculiar stars, abundances of Mg, Na and Al are based on NLTE kineticequilibrium calculations applied to spectrum synthesis methods. Results.The relation between [Na/Mg] and [Fe/H] is a continuousenrichment through all three Galactic populations spanning a range ofvalues between a metal-poor plateau at [ Na/Mg] = -0.7 and solar values.[Al/Mg] displays a step-like difference between stars of the Galactichalo with overline[Al/Mg] ˜ -0.45 and the two disk populations withoverline[Al/Mg] ˜ +0.10. [Al/Mg] ratios, together with the [Mg/Fe]ratios, asymmetric drift velocities V, and stellar evolutionary ages,make possible the individual discrimination between stars of the thickdisk and the halo. At present, this evidence is limited by the smallnumber of stars, and by the theoretical and empirical uncertainties ofstellar age determinations, but it achieves a high significance. Conclusions.While the stellar sample is not complete with respect tospace volume, the resulting abundances indicate the necessity to revisecurrent models of chemical evolution to allow for an adequate productionof Al in early stellar generations.

Effective temperature scale and bolometric corrections from 2MASS photometry
We present a method to determine effective temperatures, angularsemi-diameters and bolometric corrections for population I and II FGKtype stars based on V and 2MASS IR photometry. Accurate calibration isaccomplished by using a sample of solar analogues, whose averagetemperature is assumed to be equal to the solar effective temperature of5777 K. By taking into account all possible sources of error we estimateassociated uncertainties to better than 1% in effective temperature andin the range 1.0-2.5% in angular semi-diameter for unreddened stars.Comparison of our new temperatures with other determinations extractedfrom the literature indicates, in general, remarkably good agreement.These results suggest that the effective temperaure scale of FGK starsis currently established with an accuracy better than 0.5%-1%. Theapplication of the method to a sample of 10 999 dwarfs in the Hipparcoscatalogue allows us to define temperature and bolometric correction (Kband) calibrations as a function of (V-K), [m/H] and log g. Bolometriccorrections in the V and K bands as a function of T_eff, [m/H] and log gare also given. We provide effective temperatures, angularsemi-diameters, radii and bolometric corrections in the V and K bandsfor the 10 999 FGK stars in our sample with the correspondinguncertainties.

Sulfur Abundances in Metal-Poor Stars Based on OAO-1.88m/HIDES Spectra
The LTE abundances of sulfur (S) of 21 metal-poor stars and one normalstar were explored in the metallicity range of -3 < [Fe/H] ≤ 0,based on the equivalent widths of the S I (1) 9212, 9237Å and S I(6) 8693, 9894Å lines measured on high-resolution spectra, whichwere observed by the OAO 1.88-m telescope equipped with HIDES. Our mainresults are: (1) The abundances derived from the S I (6) lines areconsistent with those from the S I (1) lines among our sample stars inthe range of [Fe/H] > -2 with an average difference of +0.03 ±0.05 dex, whereas a significant discrepancy is observed in the range of[Fe/H] ≤ -2. (2) The behavior of [S(6)/Fe], versus [Fe/H] of ourhalo sample stars exhibits a nearly flat trend with an average of +0.62± 0.09 dex in the range of -3 < [Fe/H] < -1.25, and shows adistribution around +0.29 dex in -1.25 ≤ [Fe/H] ≤ -0.7. Oursample stars with -1.25 ≤ [Fe/H] ≤ -0.5 follow an increasingtrend with decreasing [Fe/H]. The behavior of [S(1)/Fe] of our samplestars also shows essentially the same trend as [S(6)/Fe], though it isquantitatively different. (3) The S behavior in the range of -3 <[Fe/H] ≤ 0 inferred from the abundances of multiplets 6 and 1 arequalitatively consistent with each other, and may be represented by acombination of a nearly flat trend and a linearly increasing trend withdecreasing [Fe/H]. A transition of the trend is likely to occur at[Fe/H] ˜ -1.5 dex.

Chemical Composition in the Globular Cluster M71 from Keck HIRES Spectra of Turnoff Stars
We have made observations with the Keck I telescope and HIRES at aresolution of ~45,000 of five nearly identical stars at the turnoff ofthe metal-rich globular cluster M71. We derive stellar parameters andabundances of several elements. Our mean Fe abundance,[Fe/H]=-0.80+/-0.02, is in excellent agreement with previous clusterdeterminations from both giants and near-turnoff stars. There is noclear evidence for any star-to-star abundance differences orcorrelations in our sample. Abundance ratios of the Fe peak elements(Cr, Ni) are similar to Fe. The turnoff stars in M71 have remarkablyconsistent enhancements of 0.2-0.3 dex in [Si/Fe], [Ca/Fe], and [Ti/Fe],like the red giants. Our [Mg/Fe] ratio is somewhat lower than thatsuggested by other studies. We compare our mean abundances for the fiveM71 stars with field stars of similar metallicity [Fe/H]: eight withhalo kinematics and 17 with disk kinematics. The abundances of theα-fusion products (Mg, Si, Ca, Ti) agree with both samples butseem a closer match to the disk stars. The Mg abundance in M71 is at thelower edge of the disk and halo samples. The neutron-capture elements, Yand Ba, are enhanced relative to solar in the M71 turnoff stars. Ourratio [Ba/Fe] is similar to that of the halo field stars but a factor of2 above that for the disk field stars. The important [Ba/Y] ratio issignificantly lower than M71 giant values; the precluster material mayhave been exposed to a higher neutron flux than the disk stars orself-enrichment has occurred subsequent to cluster star formation. TheNa content of the M71 turnoff stars is remarkably similar to that in thedisk field stars but more than a factor of 2 higher than the halo fieldstar sample. We find [Na/Fe]=+0.14+/-0.04 with a spread less than halfof that found in the red giants in M71. Excluding Mg, the lack ofintracluster α-element variations (turnoff vis-à-visgiants) suggests that the polluting material needed to explain theabundance patterns in M71 did not arise from explosive nucleosynthesisbut in a more traditional s-process environment such as AGB stars. Thedetermination of light s-peak abundances should reveal whether thispollution occurred before or after cluster formation.

Sulphur abundance in Galactic stars
We investigate sulphur abundance in 74 Galactic stars by using highresolution spectra obtained at ESO VLT and NTT telescopes. For the firsttime the abundances are derived, where possible, from three opticalmultiplets: Mult. 1, 6, and 8. By combining our own measurements withdata in the literature we assemble a sample of 253 stars in themetallicity range -3.2  [Fe/H]  +0.5. Two important features,which could hardly be detected in smaller samples, are obvious from thislarge sample: 1) a sizeable scatter in [S/Fe] ratios around [Fe/H]˜-1; 2) at low metallicities we observe stars with [S/Fe]˜ 0.4, aswell as stars with higher [S/Fe] ratios. The latter do not seem to bekinematically different from the former ones. Whether the latter findingstems from a distinct population of metal-poor stars or simply from anincreased scatter in sulphur abundances remains an open question.

Abundance trends in kinematical groups of the Milky Way's disk
We have compiled a large catalogue of metallicities and abundance ratiosfrom the literature in order to investigate abundance trends of severalalpha and iron peak elements in the thin disk and the thick disk of theGalaxy. The catalogue includes 743 stars with abundances of Fe, O, Mg,Ca, Ti, Si, Na, Ni and Al in the metallicity range -1.30 < [Fe/H]< +0.50. We have checked that systematic differences betweenabundances measured in the different studies were lower than randomerrors before combining them. Accurate distances and proper motions fromHipparcos and radial velocities from several sources have been retreivedfor 639 stars and their velocities (U, V, W) and galactic orbits havebeen computed. Ages of 322 stars have been estimated with a Bayesianmethod of isochrone fitting. Two samples kinematically representative ofthe thin and thick disks have been selected, taking into account theHercules stream which is intermediate in kinematics, but with a probabledynamical origin. Our results show that the two disks are chemicallywell separated, they overlap greatly in metallicity and both showparallel decreasing alpha elements with increasing metallicity, in theinterval -0.80 < [Fe/H] < -0.30. The Mg enhancement with respectto Fe of the thick disk is measured to be 0.14 dex. An even largerenhancement is observed for Al. The thick disk is clearly older than thethin disk with tentative evidence of an AMR over 2-3 Gyr and a hiatus instar formation before the formation of the thin disk. We do not observea vertical gradient in the metallicity of the thick disk. The Herculesstream has properties similar to that of the thin disk, with a widerrange of metallicity. Metal-rich stars assigned to the thick disk andsuper-metal-rich stars assigned to the thin disk appear as outliers inall their properties.

Stars of Extragalactic Origin in the Solar Neighborhood
For 77 main-sequence F-G stars in the solar neighborhood with publishediron, magnesium, and europium abundances determined from high-dispersionspectra and with the ages estimated from theoretical isochrones, wecalculated the spatial velocities using Hipparcos data and the Galacticorbital elements. A comparison with the orbital elements of the globularclusters that are known to have been accreted by our Galaxy in the pastreveals stars of extragalactic origin. We show that the abundance ratiosof r- and alpha-elements in all the accreted stars differ sharply fromthose in the stars that are genetically associated with the Galaxy.According to current theoretical models, europium is produced mainly inlow-mass type-II supernovae (SNe II), while magnesium is synthesized inlarge quantities in high-mass SN II progenitors. Since all the oldaccreted stars of our sample exhibit a significant Eu overabundancerelative to Mg, we conclude that the maximum masses of the SN IIprogenitors outside the Galaxy were much lower than those inside it. Onthe other hand, only a small number of young accreted stars exhibit lownegative ratios [Eu/Mg] < 0. This can be explained by the delay ofprimordial star formation and the explosions of high-mass SNe II in arelatively small part of extragalactic space. We provide evidence thatthe interstellar medium was weakly mixed at the early evolutionarystages of the Galaxy formed from a single protogalactic cloud, and thatthe maximum mass of the SN II progenitors increased in it with timesimultaneously with the increase in mean metallicity.

Neutron-Capture Elements in Halo, Thick-Disk, and Thin-Disk Stars: Neodymium
We have derived the LTE neodymium abundances in 60 cool stars withmetallicities [Fe/H] from 0.25 to -1.71 by applying a synthetic-spectrumanalysis to spectroscopic observations of NdII lines with a resolutionof λ/Δλ⋍60 000 and signal-to-noise ratios of100 200. We have improved the atomic parameters of NdII and blendinglines by analyzing the corresponding line pro files in the solarspectrum. Neodymium is overabundant with respect to iron in halo stars,[Nd/Fe]=0.33±0.09, with the [Nd/Fe] ratio decreasingsystematically with metallicity when [Fe/H]>-1. This reflects anonset of efficient iron production in type I supernovae during theformation of the thick disk. The [Nd/Ba] and [Nd/Eu] abundance ratiosbehave differently in halo, thick-disk, and thin-disk stars. Theobserved abundance ratios in halo stars, [Nd/Ba]=0.34±0.08 and[Nd/Eu]=-0.27±0.05, agree within the errors with the ratios ofthe elemental yields for the r-process. These results support theconclusion of other authors based on analyses of other elements that ther-process played the dominant role in the synthesis of heavy elementsduring the formation of the halo. The [Nd/Ba] and [Nd/Eu] ratios forthick-disk stars are almost independent of metallicity([Nd/Ba]=0.28(±0.03)-0.01(±0.04) [Fe/H] and[Nd/Eu]=-0.13(±0.03)+0.05(±0.04) [Fe/H]) but are smallerin absolute value than the corresponding ratios for halo stars,suggesting that the synthesis of s-process nuclei started during theformation of the thick disk. The s-process is estimated to havecontributed ⋍30% of the neodymium produced during this stage ofthe evolution of the Galaxy. The [Nd/Ba] ratio decreases abruptly by0.17 dex in the transition from the thick to the thin disk. Thesystematic decrease of [Nd/Ba] and increase of [Nd/Eu] with increasingmetallicity of thin-disk stars point toward a dominant role of thes-process in the synthesis of heavy elements during this epoch.

The Indo-US Library of Coudé Feed Stellar Spectra
We have obtained spectra for 1273 stars using the 0.9 m coudéfeed telescope at Kitt Peak National Observatory. This telescope feedsthe coudé spectrograph of the 2.1 m telescope. The spectra havebeen obtained with the no. 5 camera of the coudé spectrograph anda Loral 3K×1K CCD. Two gratings have been used to provide spectralcoverage from 3460 to 9464 Å, at a resolution of ~1 Å FWHMand at an original dispersion of 0.44 Å pixel-1. For885 stars we have complete spectra over the entire 3460 to 9464 Åwavelength region (neglecting small gaps of less than 50 Å), andpartial spectral coverage for the remaining stars. The 1273 stars havebeen selected to provide broad coverage of the atmospheric parametersTeff, logg, and [Fe/H], as well as spectral type. The goal ofthe project is to provide a comprehensive library of stellar spectra foruse in the automated classification of stellar and galaxy spectra and ingalaxy population synthesis. In this paper we discuss thecharacteristics of the spectral library, viz., details of theobservations, data reduction procedures, and selection of stars. We alsopresent a few illustrations of the quality and information available inthe spectra. The first version of the complete spectral library is nowpublicly available from the National Optical Astronomy Observatory(NOAO) via ftp and http.

Synthetic Lick Indices and Detection of α-enhanced Stars. II. F, G, and K Stars in the -1.0 < [Fe/H] < +0.50 Range
We present an analysis of 402 F, G, and K solar neighborhood stars, withaccurate estimates of [Fe/H] in the range -1.0 to +0.5 dex, aimed at thedetection of α-enhanced stars and at the investigation of theirkinematical properties. The analysis is based on the comparison of 571sets of spectral indices in the Lick/IDS system, coming from fourdifferent observational data sets, with synthetic indices computed withsolar-scaled abundances and with α-element enhancement. We useselected combinations of indices to single out α-enhanced starswithout requiring previous knowledge of their main atmosphericparameters. By applying this approach to the total data set, we obtain alist of 60 bona fide α-enhanced stars and of 146 stars withsolar-scaled abundances. The properties of the detected α-enhancedand solar-scaled abundance stars with respect to their [Fe/H] values andkinematics are presented. A clear kinematic distinction betweensolar-scaled and α-enhanced stars was found, although a one-to-onecorrespondence to ``thin disk'' and ``thick disk'' components cannot besupported with the present data.

Nearby stars of the Galactic disk and halo. III.
High-resolution spectroscopic observations of about 150 nearby stars orstar systems are presented and discussed. The study of these and another100 objects of the previous papers of this series implies that theGalaxy became reality 13 or 14 Gyr ago with the implementation of amassive, rotationally-supported population of thick-disk stars. The veryhigh star formation rate in that phase gave rise to a rapid metalenrichment and an expulsion of gas in supernovae-driven Galactic winds,but was followed by a star formation gap for no less than three billionyears at the Sun's galactocentric distance. In a second phase, then, thethin disk - our ``familiar Milky Way'' - came on stage. Nowadays ittraces the bright side of the Galaxy, but it is also embedded in a hugecoffin of dead thick-disk stars that account for a large amount ofbaryonic dark matter. As opposed to this, cold-dark-matter-dominatedcosmologies that suggest a more gradual hierarchical buildup throughmergers of minor structures, though popular, are a poor description forthe Milky Way Galaxy - and by inference many other spirals as well - if,as the sample implies, the fossil records of its long-lived stars do notstick to this paradigm. Apart from this general picture that emergeswith reference to the entire sample stars, a good deal of the presentwork is however also concerned with detailed discussions of manyindividual objects. Among the most interesting we mention the bluestraggler or merger candidates HD 165401 and HD 137763/HD 137778, thelikely accretion of a giant planet or brown dwarf on 59 Vir in itsrecent history, and HD 63433 that proves to be a young solar analog at\tau˜200 Myr. Likewise, the secondary to HR 4867, formerly suspectednon-single from the Hipparcos astrometry, is directly detectable in thehigh-resolution spectroscopic tracings, whereas the visual binary \chiCet is instead at least triple, and presumably even quadruple. Withrespect to the nearby young stars a complete account of the Ursa MajorAssociation is presented, and we provide as well plain evidence foranother, the ``Hercules-Lyra Association'', the likely existence ofwhich was only realized in recent years. On account of its rotation,chemistry, and age we do confirm that the Sun is very typical among itsG-type neighbors; as to its kinematics, it appears however not unlikelythat the Sun's known low peculiar space velocity could indeed be thecause for the weak paleontological record of mass extinctions and majorimpact events on our parent planet during the most recent Galactic planepassage of the solar system. Although the significance of thiscorrelation certainly remains a matter of debate for years to come, wepoint in this context to the principal importance of the thick disk fora complete census with respect to the local surface and volumedensities. Other important effects that can be ascribed to this darkstellar population comprise (i) the observed plateau in the shape of theluminosity function of the local FGK stars, (ii) a small thoughsystematic effect on the basic solar motion, (iii) a reassessment of theterm ``asymmetrical drift velocity'' for the remainder (i.e. the thindisk) of the stellar objects, (iv) its ability to account for the bulkof the recently discovered high-velocity blue white dwarfs, (v) itsmajor contribution to the Sun's ˜220 km s-1 rotationalvelocity around the Galactic center, and (vi) the significant flatteningthat it imposes on the Milky Way's rotation curve. Finally we note ahigh multiplicity fraction in the small but volume-complete local sampleof stars of this ancient population. This in turn is highly suggestivefor a star formation scenario wherein the few existing single stellarobjects might only arise from either late mergers or the dynamicalejection of former triple or higher level star systems.

Stellar Chemical Signatures and Hierarchical Galaxy Formation
To compare the chemistries of stars in the Milky Way dwarf spheroidal(dSph) satellite galaxies with stars in the Galaxy, we have compiled alarge sample of Galactic stellar abundances from the literature. Whenkinematic information is available, we have assigned the stars tostandard Galactic components through Bayesian classification based onGaussian velocity ellipsoids. As found in previous studies, the[α/Fe] ratios of most stars in the dSph galaxies are generallylower than similar metallicity Galactic stars in this extended sample.Our kinematically selected stars confirm this for the Galactic halo,thin-disk, and thick-disk components. There is marginal overlap in thelow [α/Fe] ratios between dSph stars and Galactic halo stars onextreme retrograde orbits (V<-420 km s-1), but this is notsupported by other element ratios. Other element ratios compared in thispaper include r- and s-process abundances, where we find a significantoffset in the [Y/Fe] ratios, which results in a large overabundance in[Ba/Y] in most dSph stars compared with Galactic stars. Thus, thechemical signatures of most of the dSph stars are distinct from thestars in each of the kinematic components of the Galaxy. This resultrules out continuous merging of low-mass galaxies similar to these dSphsatellites during the formation of the Galaxy. However, we do not ruleout very early merging of low-mass dwarf galaxies, since up to one-halfof the most metal-poor stars ([Fe/H]<=-1.8) have chemistries that arein fair agreement with Galactic halo stars. We also do not rule outmerging with higher mass galaxies, although we note that the LMC and theremnants of the Sgr dwarf galaxy are also chemically distinct from themajority of the Galactic halo stars. Formation of the Galaxy's thickdisk by heating of an old thin disk during a merger is also not ruledout; however, the Galaxy's thick disk itself cannot be comprised of theremnants from a low-mass (dSph) dwarf galaxy, nor of a high-mass dwarfgalaxy like the LMC or Sgr, because of differences in chemistry.The new and independent environments offered by the dSph galaxies alsoallow us to examine fundamental assumptions related to thenucleosynthesis of the elements. The metal-poor stars ([Fe/H]<=-1.8)in the dSph galaxies appear to have lower [Ca/Fe] and [Ti/Fe] than[Mg/Fe] ratios, unlike similar metallicity stars in the Galaxy.Predictions from the α-process (α-rich freeze-out) would beconsistent with this result if there have been a lack of hypernovae indSph galaxies. The α-process could also be responsible for thevery low Y abundances in the metal-poor stars in dSph's; since [La/Eu](and possibly [Ba/Eu]) are consistent with pure r-process results, thelow [Y/Eu] suggests a separate r-process site for this light(first-peak) r-process element. We also discuss SNe II rates and yieldsas other alternatives, however. In stars with higher metallicities([Fe/H]>=-1.8), contributions from the s-process are expected; [(Y,La, and Ba)/Eu] all rise as expected, and yet [Ba/Y] is still muchhigher in the dSph stars than similar metallicity Galactic stars. Thisresult is consistent with s-process contributions from lower metallicityAGB stars in dSph galaxies, and is in good agreement with the slowerchemical evolution expected in the low-mass dSph galaxies relative tothe Galaxy, such that the build-up of metals occurs over much longertimescales. Future investigations of nucleosynthetic constraints (aswell as galaxy formation and evolution) will require an examination ofmany stars within individual dwarf galaxies.Finally, the Na-Ni trend reported in 1997 by Nissen & Schuster isconfirmed in Galactic halo stars, but we discuss this in terms of thegeneral nucleosynthesis of neutron-rich elements. We do not confirm thatthe Na-Ni trend is related to the accretion of dSph galaxies in theGalactic halo.

Empirically Constrained Color-Temperature Relations. II. uvby
A new grid of theoretical color indices for the Strömgren uvbyphotometric system has been derived from MARCS model atmospheres and SSGsynthetic spectra for cool dwarf and giant stars having-3.0<=[Fe/H]<=+0.5 and 3000<=Teff<=8000 K. Atwarmer temperatures (i.e., 8000-2.0. To overcome thisproblem, the theoretical indices at intermediate and high metallicitieshave been corrected using a set of color calibrations based on fieldstars having well-determined distances from Hipparcos, accurateTeff estimates from the infrared flux method, andspectroscopic [Fe/H] values. In contrast with Paper I, star clustersplayed only a minor role in this analysis in that they provided asupplementary constraint on the color corrections for cool dwarf starswith Teff<=5500 K. They were mainly used to test thecolor-Teff relations and, encouragingly, isochrones thatemploy the transformations derived in this study are able to reproducethe observed CMDs (involving u-v, v-b, and b-y colors) for a number ofopen and globular clusters (including M67, the Hyades, and 47 Tuc)rather well. Moreover, our interpretations of such data are verysimilar, if not identical, with those given in Paper I from aconsideration of BV(RI)C observations for the sameclusters-which provides a compelling argument in support of thecolor-Teff relations that are reported in both studies. Inthe present investigation, we have also analyzed the observedStrömgren photometry for the classic Population II subdwarfs,compared our ``final'' (b-y)-Teff relationship with thosederived empirically in a number of recent studies and examined in somedetail the dependence of the m1 index on [Fe/H].Based, in part, on observations made with the Nordic Optical Telescope,operated jointly on the island of La Palma by Denmark, Finland, Iceland,Norway, and Sweden, in the Spanish Observatorio del Roque de losMuchachos of the Instituto de Astrofisica de Canarias.Based, in part, on observations obtained with the Danish 1.54 mtelescope at the European Southern Observatory, La Silla, Chile.

The Geneva-Copenhagen survey of the Solar neighbourhood. Ages, metallicities, and kinematic properties of ˜14 000 F and G dwarfs
We present and discuss new determinations of metallicity, rotation, age,kinematics, and Galactic orbits for a complete, magnitude-limited, andkinematically unbiased sample of 16 682 nearby F and G dwarf stars. Our˜63 000 new, accurate radial-velocity observations for nearly 13 500stars allow identification of most of the binary stars in the sampleand, together with published uvbyβ photometry, Hipparcosparallaxes, Tycho-2 proper motions, and a few earlier radial velocities,complete the kinematic information for 14 139 stars. These high-qualityvelocity data are supplemented by effective temperatures andmetallicities newly derived from recent and/or revised calibrations. Theremaining stars either lack Hipparcos data or have fast rotation. Amajor effort has been devoted to the determination of new isochrone agesfor all stars for which this is possible. Particular attention has beengiven to a realistic treatment of statistical biases and errorestimates, as standard techniques tend to underestimate these effectsand introduce spurious features in the age distributions. Our ages agreewell with those by Edvardsson et al. (\cite{edv93}), despite severalastrophysical and computational improvements since then. We demonstrate,however, how strong observational and theoretical biases cause thedistribution of the observed ages to be very different from that of thetrue age distribution of the sample. Among the many basic relations ofthe Galactic disk that can be reinvestigated from the data presentedhere, we revisit the metallicity distribution of the G dwarfs and theage-metallicity, age-velocity, and metallicity-velocity relations of theSolar neighbourhood. Our first results confirm the lack of metal-poor Gdwarfs relative to closed-box model predictions (the ``G dwarfproblem''), the existence of radial metallicity gradients in the disk,the small change in mean metallicity of the thin disk since itsformation and the substantial scatter in metallicity at all ages, andthe continuing kinematic heating of the thin disk with an efficiencyconsistent with that expected for a combination of spiral arms and giantmolecular clouds. Distinct features in the distribution of the Vcomponent of the space motion are extended in age and metallicity,corresponding to the effects of stochastic spiral waves rather thanclassical moving groups, and may complicate the identification ofthick-disk stars from kinematic criteria. More advanced analyses of thisrich material will require careful simulations of the selection criteriafor the sample and the distribution of observational errors.Based on observations made with the Danish 1.5-m telescope at ESO, LaSilla, Chile, and with the Swiss 1-m telescope at Observatoire deHaute-Provence, France.Complete Tables 1 and 2 are only available in electronic form at the CDSvia anonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) or viahttp://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/418/989

Sulphur and zinc abundances in Galactic stars and damped Lyα systems
High resolution spectra of 34 halo population dwarf and subgiant starshave been obtained with VLT/UVES and used to derive sulphur abundancesfrom the λ λ 8694.0, 8694.6 and λ λ 9212.9,9237.5 S I lines. In addition, iron abundances have been determined from19 Fe II lines and zinc abundances from the λ λ 4722.2,4810.5 lines. The abundances are based on a classical 1D, LTE modelatmosphere analysis, but effects of 3D hydrodynamical modelling on the[S/Fe], [Zn/Fe] and [S/Zn] ratios are shown to be small. We find thatmost halo stars with metallicities in the range -3.2 < [Fe/H] <-0.8 have a near-constant [S/Fe] ≃ +0.3; a least square fit to[S/Fe] vs. [Fe/H] shows a slope of only -0.04 ± 0.01. Among halostars with -1.2 < [Fe/H] < -0.8 the majority have [S/Fe] ≃+0.3, but two stars (previously shown to have low α/Fe ratios)have [S/Fe] ≃ 0.0. For disk stars with [Fe/H] > -1, [S/Fe]decreases with increasing [Fe/H] . Hence, sulphur behaves like othertypical α-capture elements, Mg, Si and Ca. Zinc, on the otherhand, traces iron over three orders of magnitude in [Fe/H], althoughthere is some evidence for a small systematic Zn overabundance ([Zn/Fe]≃ +0.1) among metal-poor disk stars and for halo stars with [Fe/H]< -2.0. Recent measurements of S and Zn in ten damped Lyαsystems (DLAs) with redshifts between 1.9 and 3.4 and zinc abundances inthe range -2.1 < [Zn/H] < -0.15 show an offset relative to the[S/Zn] - [Zn/H] relation in Galactic stars. Possible reasons for thisoffset are discussed, including low and intermittent star formationrates in DLAs.Based on observations collected at the European Southern Observatory,Chile (ESO No. 67.D-0106).Table A1 is only available in electronic form at the CDS via anonymousftp to cdsarc.u-strasbg.fr (130.79.128.5) or viahttp://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/415/993

The evolution of the C/O ratio in metal-poor halo stars
We report new measurements of carbon and oxygen abundances in 34 F and Gdwarf and subgiant stars belonging to the halo population and spanning arange of metallicity from [Fe/H] = -0.7 to -3.2 . The survey is based onobservations of four permitted lines of C I near 9100 Å and the OI,λ 7774 triplet, all recorded at high signal-to-noise ratioswith the UVES echelle spectrograph on the ESO VLT. The line equivalentwidths were analysed with the 1D, LTE, MARCS model atmosphere code todeduce C and O abundances; corrections due to non-LTE and 3D effects arediscussed. When combined with similar published data for disk stars, ourresults confirm the metallicity dependence of the C/O ratio known fromprevious stellar and interstellar studies: C/O drops by a factor of˜3-4 as O/H decreases from solar to ˜1/10 solar. Analysed withinthe context of standard models for the chemical evolution of the solarvicinity, this drop results from the metallicity dependence of the Cyields from massive stars with mass loss, augmented by the delayedrelease of C from stars of low and intermediate mass. The former is,however, always the dominant factor. Our survey has also uncoveredtentative evidence to suggest that, as the oxygen abundance decreasesbelow [O/H] = -1, [C/O] may not remain constant at [C/O] = -0.5, aspreviously thought, but increase again, possibly approaching near-solarvalues at the lowest metallicities ([O/H] ≲ -3). With the currentdataset this is no more than a 3σ effect and it may be due tometallicity-dependent non-LTE corrections to the [C/O] ratio which havenot been taken into account. However, its potential importance as awindow on the nucleosynthesis by Population III stars is a strongincentive for future work, both observational and theoretical, to verifyits reality.Based on observations collected at the European Southern Observatory,Chile (ESO No. 67.D-0106).

Abundances of Na, Mg and Al in nearby metal-poor stars
To determine the population membership of nearby stars we exploreabundance results obtained for the light neutron-rich elements23Na and 27 Al in a small sample of moderatelymetal-poor stars. Spectroscopic observations are limited to the solarneighbourhood so that gravities can be determined from HIPPARCOSparallaxes, and the results are confronted with those for a separatesample of more metal-poor typical halo stars. Following earlierinvestigations, the abundances of Na, Mg and Al have been derived fromNLTE statistical equilibrium calculations used as input to line profilesynthesis. Compared with LTE the abundances require systematiccorrections, with typical values of +0.05 for [Mg/Fe], -0.1 for [Na/Fe]and +0.2 for [Al/Fe] in thick disk stars where [Fe/H] ˜ -0.6. Inmore metal-poor halo stars these values reach +0.1, -0.4, and +0.5,respectively, differences that can no longer be ignored.After careful selection of a clean subsample free from suspected orknown binaries and peculiar stars, we find that [Na/Mg] and [Al/Mg], incombination with [Mg/Fe], space velocities and stellar evolutionaryages, make possible an individual discrimination between thick disk andhalo stars. At present, this evidence is limited by the small number ofstars analyzed. We identify a gap at [Al/Mg] ˜ -0.15 and [Fe/H]˜ -1.0 that isolates stars of the thick disk from those in the halo.A similar separation occurs at [Na/Mg] ˜ -0.4. We do not confirm theage gap between thin and thick disk found by Fuhrmann. Instead we findan age boundary between halo and thick disk stars, however, with anabsolute value of 14 Gyr that must be considered as preliminary. Whilethe stellar sample is by no means complete, the resulting abundancesindicate the necessity to revise current models of chemical evolutionand/or stellar nucleosynthesis to allow for an adequate production ofneutron-rich species in early stellar generations.Based on observations collected at the German-Spanish AstronomicalCenter, Calar Alto (CAHA H01-2.2-002) and at the European SouthernObservatory, Chile (ESO 67.D-0086).

New Metallicity Calibration Down to [Fe/H] = -2.75 dex
We have taken 88 dwarfs, covering the colour-index interval 0.37 <=(B-V)0 <= 1.07mag, with metallicities -2.70 <= [Fe/H]<= +0.26dex, from three different sources for new metallicitycalibration. The catalogue of Cayrel de Stroble et al. (2001), whichincludes 65% of the stars in our sample, supplies detailed informationon abundances for stars with determination based on high-resolutionspectroscopy. In constructing the new calibration we have used as`corner stones' 77 stars which supply at least one of the followingconditions: (i) the parallax is larger than 10mas (distance relative tothe Sun less than 100pc) and the galactic latitude is absolutely higherthan 30° (ii) the parallax is rather large, if the galactic latitudeis absolutely low and vice versa. Contrary to previous investigations, athird-degree polynomial is fitted for the new calibration: [Fe/H]=0.10 -2.76δ - 24.04δ2 + 30.00δ3. Thecoefficients were evaluated by the least-squares method, without regardto the metallicity of Hyades. However, the constant term is in the rangeof metallicity determined for this cluster, i.e.0.08<=[Fe/H]<=0.11dex. The mean deviation and the mean error inour work are equal to those of Carney (1979), for [Fe/H] >= -1.75dexwhere Carney's calibration is valid

Saturated Hydrocarbons in Comet 153P/Ikeya-Zhang: Ethane, Methane, and Monodeuterio-Methane
Emissions of the methane ν3 band and the ethaneν7 band were detected in the high-dispersion infraredspectra of comet 153P/Ikeya-Zhang taken by the Subaru Telescope with theInfrared Camera and Spectrograph (IRCS) on 2002 May 28 and 29 UT. Therotational temperature is estimated to be about 40-50 K fromR0 and R1 lines of the methane ν3band. The production rates of methane and ethane were estimated byapplying the rotational temperature of 50 K. Resultant production ratesof methane and ethane are (2.13+/-0.40)×1026 and(1.75+/-0.48)×1026 molecules s-1,respectively. The abundance ratio between ethane and methane is0.82+/-0.27, which is comparable with other comets within error bars.Although the emissions of monodeuterio-methane (CH3D) weresearched for carefully, there is no evidence of them. The 2 σ (95%confidence) upper limit of the CH3D/CH4 ratio is0.3 in comet 153P/Ikeya-Zhang. Comparing the relative abundance ofmethane and ethane in the interstellar ices, we discussed the formationconditions of cometary nuclei.

Improved Astrometry and Photometry for the Luyten Catalog. II. Faint Stars and the Revised Catalog
We complete construction of a catalog containing improved astrometry andnew optical/infrared photometry for the vast majority of NLTT starslying in the overlap of regions covered by POSS I and by the secondincremental Two Micron All Sky Survey (2MASS) release, approximately 44%of the sky. The epoch 2000 positions are typically accurate to 130 mas,the proper motions to 5.5 mas yr-1, and the V-J colors to0.25 mag. Relative proper motions of binary components are measured to 3mas yr-1. The false-identification rate is ~1% for11<~V<~18 and substantially less at brighter magnitudes. Theseimprovements permit the construction of a reduced proper-motion diagramthat, for the first time, allows one to classify NLTT stars intomain-sequence (MS) stars, subdwarfs (SDs), and white dwarfs (WDs). We inturn use this diagram to analyze the properties of both our catalog andthe NLTT catalog on which it is based. In sharp contrast to popularbelief, we find that NLTT incompleteness in the plane is almostcompletely concentrated in MS stars, and that SDs and WDs are detectedalmost uniformly over the sky δ>-33deg. Our catalogwill therefore provide a powerful tool to probe these populationsstatistically, as well as to reliably identify individual SDs and WDs.

Interrelations between V il and S tr photometric systems: The luminosity indicator (v - X)
Using the largest database of near-IR Ca II Triplet indices currentlyavailable (Cenarro et al. \cite{Cenarro01a},b), we confirm our findingabout the influence of the Ca II stellar lines on the X magnitude ofthe Vilnius photometric system. This effect is significant for spectralsub-classes from early F until mid K. For this spectral range there is alinear relation between the v-X index and the strength of the infraredCa II Triplet, which implies that the Ca II H&K lines shouldinfluence the difference in a similar way. For the spectral intervalstudied, v-X repeats the behavior of the Ca II Triplet with respect togravity, temperature and metallicity. The Ca II Triplet lines are apowerful diagnostic of the stellar populations in galaxies because oftheir sensitivity to the main stellar atmospheric parameters. Being mucheasily achievable observationally and virtually reddening free, the v-Xindex may find similar applications. v-X is log g sensitive butadditional means are required to break the dwarf - giant duplicity. Forthis purpose we have studied the variation of thev(Strömgren)-B(Johnson) index with gravity, temperature and theequivalent width of the Ca II Triplet. Sincev(Strömgren)-B(Johnson) have a none overlapping variation with theCa II Triplet the dwarfs and giants may be separated and Teffand log g may be estimated. The v(Strömgren)-B(Johnson) index hasfurthermore the advantage that E(v-B) ~ 0.25E(B-V).Based on CDS data.

Abundances for metal-poor stars with accurate parallaxes. I. Basic data
We present element-to-element abundance ratios measured from highdispersion spectra for 150 field subdwarfs and early subgiants withaccurate Hipparcos parallaxes (errors <20%). For 50 stars new spectrawere obtained with the UVES on Kueyen (VLT UT2), the McDonald 2.7 mtelescope, and SARG at TNG. Additionally, literature equivalent widthswere taken from the works by Nissen & Schuster, Fulbright, andProchaska et al. to complement our data. The whole sample includes boththick disk and halo stars (and a few thin disk stars); most stars havemetallicities in the range -2<[Fe/H]<-0.6. We found our data, thatof Nissen & Schuster, and that of Prochaska to be of comparablequality; results from Fulbright scatter a bit more, but they are stillof very good quality and are extremely useful due to the large size ofhis sample. The results of the present analysis will be used inforthcoming papers to discuss the chemical properties of thedissipational collapse and accretion components of our Galaxy.Based in part on data collected at the European Southern Observatory,Chile, at the MacDonald Observatory, Texas, USA, and at the TelescopioNazionale Galileo, Canary Island, INAF,Italy-Spain.}\fnmsep\thanks{Table 1 is only available in electronic format the CDS via anonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) orvia\resizebox{8.8cm}{2.2mm}htpp://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/404/187}

Oxygen line formation in late-F through early-K disk/halo stars. Infrared O I triplet and [O I] lines
In order to investigate the formation of O I 7771-5 and [O I] 6300/6363lines, extensive non-LTE calculations for neutral atomic oxygen werecarried out for wide ranges of model atmosphere parameters, which areapplicable to early-K through late-F halo/disk stars of variousevolutionary stages.The formation of the triplet O I lines was found to be well described bythe classical two-level-atom scattering model, and the non-LTEcorrection is practically determined by the parameters of theline-transition itself without any significant relevance to the detailsof the oxygen atomic model. This simplifies the problem in the sensethat the non-LTE abundance correction is essentially determined only bythe line-strength (Wlambda ), if the atmospheric parametersof Teff, log g, and xi are given, without any explicitdependence of the metallicity; thus allowing a useful analytical formulawith tabulated numerical coefficients. On the other hand, ourcalculations lead to the robust conclusion that LTE is totally valid forthe forbidden [O I] lines.An extensive reanalysis of published equivalent-width data of O I 7771-5and [O I] 6300/6363 taken from various literature resulted in theconclusion that, while a reasonable consistency of O I and [O I]abundances was observed for disk stars (-1 <~ [Fe/H] <~ 0), theexistence of a systematic abundance discrepancy was confirmed between OI and [O I] lines in conspicuously metal-poor halo stars (-3 <~[Fe/H] <~ -1) without being removed by our non-LTE corrections, i.e.,the former being larger by ~ 0.3 dex at -3 <~ [Fe/H] <~ -2.An inspection of the parameter-dependence of this discordance indicatesthat the extent of the discrepancy tends to be comparatively lessenedfor higher Teff/log g stars, suggesting the preference ofdwarf (or subgiant) stars for studying the oxygen abundances ofmetal-poor stars.Tables 2, 5, and 7 are only available in electronic form, at the CDS viaanonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) or viahttp://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/402/343 and Table\ref{tab3} is only available in electronic form athttp://www.edpsciences.org

3D kinematics of white dwarfs from the SPY project
We present kinematics of a sample of 107 DA white dwarfs from the SPYproject (ESO SN Ia Progenitor surveY) and discuss kinematic criteria fora distinction of thin disk, thick disk, and halo populations. This isthe first homogeneous sample of white dwarfs for which 3D space motionshave been determined.Since the percentage of old stars among white dwarfs is higher thanamong main-sequence stars, they are presumably valuable tools in studiesof old populations such as the halo and the thick disk. Studies of whitedwarf kinematics can help to determine the fraction of the total mass ofour Galaxy contained in the form of thick disk and halo white dwarfs, anissue which is still under discussion.Radial velocities and spectroscopic distances obtained by the SPYproject are combined with our measurements of proper motions to derive3D space motions. Galactic orbits and further kinematic parameters arecomputed. We calculate individual errors of kinematic parameters bymeans of a Monte Carlo error propagation code. Our kinematic criteriafor assigning population membership are deduced from a sample of F and Gstars taken from the literature for which chemical criteria can be usedto distinguish between thin disk, thick disk and halo.Candidates for thick disk and halo members are selected in a first stepfrom the classical U-V-velocity diagram. Our final assignment ofpopulation membership is based on orbits and position in theJz-eccentricity diagram. We find four halo and twelve thickdisk white dwarfs.We also present a systematic study of the effects of ignoring the radialvelocity in kinematic investigations.Based on observations obtained at the Paranal Observatory of theEuropean Southern Observatory for programs 165.H-0588 and 167.D-0407.Tables 1 and 2 are only available in electronic form at the CDS viaanonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) or viahttp://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/400/877Figures 8, 10-12, 14-16, 19, 20 are only available in electronic form athttp://www.edpsciences.org

Statistical cataloging of archival data for luminosity class IV-V stars. II. The epoch 2001 [Fe/H] catalog
This paper describes the derivation of an updated statistical catalog ofmetallicities. The stars for which those metallicities apply are ofspectral types F, G, and K, and are on or near the main sequence. Theinput data for the catalog are values of [Fe/H] published before 2002February and derived from lines of weak and moderate strength. Theanalyses used to derive the data have been based on one-dimensional LTEmodel atmospheres. Initial adjustments which are applied to the datainclude corrections to a uniform temperature scale which is given in acompanion paper (see Taylor \cite{t02}). After correction, the data aresubjected to a statistical analysis. For each of 941 stars considered,the results of that analysis include a mean value of [Fe/H], an rmserror, an associated number of degrees of freedom, and one or moreidentification numbers for source papers. The catalog of these resultssupersedes an earlier version given by Taylor (\cite{t94b}).Catalog is only available in electronic form at the CDS via anonymousftp cdsarc.u-strasbg.fr (130.79.128.5) or viahttp://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/398/731

Statistical cataloging of archival data for luminosity class IV-V stars. I. The epoch 2001 temperature catalog
This paper is one of a pair in which temperatures and metallicitycatalogs for class IV-V stars are considered. The temperature catalogdescribed here is derived from a calibration based on stellar angulardiameters. If published calibrations of this kind are compared by usingcolor-index transformations, temperature-dependent differences among thecalibrations are commonly found. However, such differences are minimizedif attention is restricted to calibrations based on Johnson V-K. Acalibration of this sort from Di Benedetto (\cite{dib98}) is thereforetested and adopted. That calibration is then applied to spectroscopicand photometric data, with the latter predominating. Cousins R-Iphotometry receives special attention because of its high precision andlow metallicity sensitivity. Testing of temperatures derived from thecalibration suggests that their accuracy and precision are satisfactory,though further testing will be warranted as new results appear. Thesetemperatures appear in the catalog as values of theta equiv5040/T(effective). Most of these entries are accompanied by measured orderived values of Cousins R-I. Entries are given for 951 stars.Catalog is only available in electronic form at the CDS via anonymousftp to cdsarc.u-strasbg.fr (130.79.128.5) or viahttp://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/398/721

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星座:武仙座
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